化工社化工社 化学情報印刷レポート · 研究参考用
Water → Citronellyl Acetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | Acetic Anhydride | HCID 7918 | — |
| 反応物 | Hexane | HCID 8058 | — |
| 生成物 | Citronellyl Acetate | HCID 9017 | — |
反応手順
To 15.6 g (0.1 mol) d1-citronellol in 20 ml of dry pyridine under nitrogen is added 11.3 ml (0.12 mol) of acetic anhydride. The reaction is stirred about 48 hours and then ice is added. After one hour, the reaction is poured into hexane and water. The organic phase is washed with 5% HCl, 2M sodium carbonate, and saturated NaCl solutions, dried over calcium sulfate and solvent removed to yield dl-citronellyl acetate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04158096 |
| 出典データセット | uspto-grants-1979_06 |
| ORD ID | ord-3ddca04c8f4a4b5885d7d10c1ae64d52 |
| 出典メモ | uspto-grants-1979_06 |