Ethanol → HCID 19907417、化合物
反応式
[CH2:1]([N:3]([CH2:21][CH3:22])[CH2:4][CH2:5][CH2:6][C:7]1[CH:12]=[CH:11][C:10]([CH2:13][CH2:14][CH2:15][N:16]([CH2:19][CH3:20])[CH2:17][CH3:18])=[CH:9][CH:8]=1)[CH3:2].[CH2:23]([I:25])[CH3:24].[CH2:26](O)[CH3:27]>>[I-:25].[I-:25].[CH2:19]([N+:16]([CH2:23][CH3:24])([CH2:17][CH3:18])[CH2:15][CH2:14][CH2:13][C:10]1[CH:9]=[CH:8][C:7]([CH2:6][CH2:5][CH2:4][N+:3]([CH2:26][CH3:27])([CH2:1][CH3:2])[CH2:21][CH3:22])=[CH:12][CH:11]=1)[CH3:20]参加物
4
実験手順
304 mg of 1,4-bis(3-diethylaminopropyl)benzene was dissolved in 2.5 ml of absolute ethanol, and after dropwise addition of 1.56 g of ethyl iodide, the mixture was refluxed for 1.5 hours in dark. After cooling, ethanol was partially removed under reduced pressure, the resulting crystal was filtered, quickly washed with ethanol and dried in vacuo to obtain 461 mg of the title compound as a colorless crystal.
後処理
- temperaturethe mixture was refluxed for 1.5 hours in dark
- temperatureAfter cooling
- customethanol was partially removed under reduced pressure