3-Methyl-2-cyclohexen-1-one → 3-Methyl-2-cyclohexen-1-one

HRID 237757

反応式

HRID 237757 の反応式
[CH3:1][C:2]1[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH:3]=1.[CH3:9][Mg]I>C(OCC)C>[CH3:1][C:2]1[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH:3]=1.[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH2:3]1

参加物

5

反応物 2

HCID 145113-Methyl-2-cyclohexen-1-oneHCID 178418373HCID 178418373、化合物

生成物 2

HCID 145113-Methyl-2-cyclohexen-1-oneHCID 76322Cyclohexanone, 3,3-dimethyl-

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

First, 3-methyl-cyclohexenone was prepared in accordance with the procedures of Jirgensons et. al., Euro. J. Med. Chem. 35 (2000) 555-565. Then, 3-methyl-cyclohexenone was reacted with methyl magnesium iodide in the presence of cuprous chloride in diethyl ether to obtain the title compound.

出典と根拠

ORDレコード
ord-f2ed5d56b2764e25bcbeb6e69c3a3e53
出典データセット
uspto-grants-2014_02
特許番号
US08642603B2

関連ノート

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