Sodium Hydroxide → Sodium diallyloxyacetate

HRID 2379242ノート

反応式

HRID 2379242 の反応式
[CH2:1]([O:4][CH:5]([O:12][CH2:13][CH:14]=[CH2:15])[C:6]([O:8]CC=C)=[O:7])[CH:2]=[CH2:3].[OH-].[Na+:17]>C1(C)C=CC=CC=1.O>[CH2:13]([O:12][CH:5]([O:4][CH2:1][CH:2]=[CH2:3])[C:6]([O-:8])=[O:7])[CH:14]=[CH2:15].[Na+:17]

参加物

5

反応物 2

HCID 14798Sodium HydroxideHCID 18958141Prop-2-en-1-yl bis[(prop-2-en-1-yl)oxy]acetate

生成物 1

HCID 5173263Sodium diallyloxyacetate

試薬・触媒・溶媒 2

HCID 962Water溶媒HCID 1140Toluene溶媒

反応条件

温度
30 °C

実験手順

21.2 g (0.1 mole) of allyl diallyloxyacetate is dissolved in 42 g of toluene then 3.92 g (98 mmoles) of sodium hydroxide dissolved in 50 g of water is introduced into this solution. This bipbase reaction medium is agitated vigorously for 30 minutes at 30° C., then decanted and the aqueous phase is collected and subjected to a vacuum distillation to eliminate the freed allyl alcohol by azeotropic distillation. The aqueous phase is then poured into acetone to precipitate the expected sodium diallyloxyacetate.

後処理

  1. additionis introduced into this solution
  2. customThis bipbase reaction medium
  3. customdecanted
  4. customthe aqueous phase is collected
  5. distillationsubjected to a vacuum distillation
  6. distillationby azeotropic distillation
  7. additionThe aqueous phase is then poured into acetone
  8. customto precipitate the expected sodium diallyloxyacetate

出典と根拠

ORDレコード
ord-6f9ae786a9ec4e03b2b3cebb29066029
出典データセット
uspto-grants-1994_11
特許番号
US05360881

反応ノート

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