Benzylamine → N-(1,1-Dimethoxypropan-2-ylidene)-1-phenylmethanamine

HRID 239125

反応式

HRID 239125 の反応式
[CH3:1][O:2][CH:3]([O:7][CH3:8])[C:4]([CH3:6])=O.S([O-])([O-])(=O)=O.[Mg+2].[CH2:15]([NH2:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[CH2:15]([N:22]=[C:4]([CH3:6])[CH:3]([O:7][CH3:8])[O:2][CH3:1])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1

参加物

4

反応物 3

HCID 7504BenzylamineHCID 24083Sulfuric acid magnesium salt (1:1)HCID 80650Pyruvic aldehyde dimethyl acetal

生成物 1

HCID 71380533N-(1,1-Dimethoxypropan-2-ylidene)-1-phenylmethanamine

実験手順

12.9 mL 1,1-dimethoxyacetone was added to 10 mL benzylamine in 100 mL petrolether. Magnesiumsulfate was added and the reaction was stirred over night at RT. The mixture was filtered and evaporated to give 18.9 g of the desired product. (M+H)+: 209

後処理

  1. filtrationThe mixture was filtered
  2. customevaporated

出典と根拠

ORDレコード
ord-b3bc05dd952240c8a50ff875b993000c
出典データセット
uspto-grants-2014_02
特許番号
US08642774B2

関連ノート

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