1-(3-Methyl-4-nitrophenyl)-1,2,4-triazole → 2-Methyl-4-[1,2,4]triazol-1-yl-phenylamine
反応式
[CH3:1][C:2]1[CH:7]=[C:6]([N:8]2[CH:12]=[N:11][CH:10]=[N:9]2)[CH:5]=[CH:4][C:3]=1[N+:13]([O-])=O>C(O)C.[Pd]>[CH3:1][C:2]1[CH:7]=[C:6]([N:8]2[CH:12]=[N:11][CH:10]=[N:9]2)[CH:5]=[CH:4][C:3]=1[NH2:13]参加物
4
実験手順
2-Methyl-4-(1,2,4-Triazol-1-yl)nitrobenzene (1.0 g, 4.9 mmol) and Pd/C (200 mg) in ethanol (50 ml) were hydrogenated at rtp for 3 days. The suspension was filtered through celite, evaporated under reduced pressure to afford a white solid (850 mg, 100%).
後処理
- filtrationThe suspension was filtered through celite
- customevaporated under reduced pressure
出典と根拠
- ORDレコード
- ord-3f9db7cc5dc84c3a98acce919db0185d
- 出典データセット
- uspto-grants-1998_09
- 特許番号
- US05801170
反応ノート
読み込み中…