Acrylic Acid → Acrylic anhydride

HRID 2396399ノート

反応式

HRID 2396399 の反応式
[C:1](Cl)(=[O:8])[C:2]1[CH:7]=CC=CC=1.[C:10]([OH:14])(=[O:13])[CH:11]=[CH2:12]>>[C:10]([O:14][C:1](=[O:8])[CH:2]=[CH2:7])(=[O:13])[CH:11]=[CH2:12]

参加物

3

実験手順

Moreover, in the case of benzoyl chloride, the resulting mixed anhydride is more reactive than benzoyl chloride. Thus, the carboxylate ion of acrylic acid preferentially reacts with the mixed anhydride to give acrylic anhydride and the benzoate ion, which subsequently reacts with unreacted benzoyl chloride to give benzoic anhydride, according to reaction scheme I.

出典と根拠

ORDレコード
ord-956688a6dc2a418baaac869d385ba646
出典データセット
uspto-grants-1996_02
特許番号
US05491244

反応ノート

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