HCID 68118111、化合物 → HCID 68119435、化合物
反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([CH3:10])=[C:6]([N:11]2[C:15](=[O:16])[C:14]3=[CH:17][C:18]([C:21]([F:24])([F:23])[F:22])=[CH:19][CH:20]=[C:13]3[C:12]2=[O:25])[CH:5]=1)([O-])=O.[H][H]>[Pd].C(O)C>[NH2:1][C:4]1[CH:9]=[CH:8][C:7]([CH3:10])=[C:6]([N:11]2[C:15](=[O:16])[C:14]3=[CH:17][C:18]([C:21]([F:24])([F:22])[F:23])=[CH:19][CH:20]=[C:13]3[C:12]2=[O:25])[CH:5]=1参加物
5
実験手順
The mixture of 3.55 g of N-(4-nitro-o-tolyl)-4-trifluoromethylphthalimide, 200 ml of 95% aqueous ethanol and 0.18 g of 5% palladium on carbon is hydrogenated at 3.1 atm. and 45° until the hydrogen uptake ceases. It is filtered, evaporated and the residue recrystallized from ethanol, to yield the N-(4-amino-o-tolyl)-4-trifluoromethylphthalimide melting at 161°-163°.