3-Hydroxycyclopentadecene → 2-Cyclopentadecenone

HRID 2398710

反応式

HRID 2398710 の反応式
[OH:1][CH:2]1[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH:4]=[CH:3]1>CCCCCCC.[O-2].[O-2].[Mn+4]>[CH:4]1[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:2](=[O:1])[CH:3]=1

参加物

4

反応物 1

HCID 544205383-Hydroxycyclopentadecene

生成物 1

HCID 540403452-Cyclopentadecenone

試薬・触媒・溶媒 2

HCID 178418406HCID 178418406、化合物触媒HCID 8900Heptane溶媒

実験手順

3-Hydroxycyclopentadecene (20.1 g) in dried n-heptane was stirred at room temperature and a total of 100 g manganese dioxide was added in four batches of 50, 25, 15 and 10 g respectively over a period of 6 hours. After 22 hours the conversion as indicated by GLC was 100%. The mixture was filtered and the filtrate was then stirred with active charcoal and refiltered. The solvent was then removed from the filtrate under reduced pressure to yield the required product.

後処理

  1. filtrationThe mixture was filtered
  2. customThe solvent was then removed from the filtrate under reduced pressure

出典と根拠

ORDレコード
ord-7aa3841707cb44ddaca7952cabb47e92
出典データセット
uspto-grants-1977_05
特許番号
US04025562

関連ノート

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