Sulfuric Acid → HCID 21432588、化合物

HRID 2399038ノート

反応式

HRID 2399038 の反応式
[N+:1]([O-:4])([O-])=[O:2].[K+].[Cl:6][C:7]1[CH:19]=[CH:18][C:10]([C:11]([C:13]2[S:14][CH:15]=[CH:16][N:17]=2)=[O:12])=[CH:9][CH:8]=1.S(=O)(=O)(O)O>>[N+:1]([C:19]1[CH:18]=[C:10]([CH:9]=[CH:8][C:7]=1[Cl:6])[C:11]([C:13]1[S:14][CH:15]=[CH:16][N:17]=1)=[O:12])([O-:4])=[O:2]

参加物

4

反応物 3

HCID 1118Sulfuric AcidHCID 24434Potassium NitrateHCID 27574032-(4-Chlorobenzoyl)thiazole

生成物 1

HCID 21432588HCID 21432588、化合物

実験手順

Potassium nitrate (2.1 g., 0.02 mol) was added in one portion to a solution of 4.5 g. (0.02 mol) of 2-(4-chlorobenzoyl)thiazole in 25 ml. of concentrated sulfuric acid. After 1 hr. the mixture was cautiously poured into 250 ml. of ice water, the product collected, washed with water and dried to yield 2-(3-nitro-4-chlorobenzoyl)thiazole as pale-yellow prisms, mp. 118°-119° (acetone-water).

後処理

  1. additionthe mixture was cautiously poured into 250 ml
  2. customof ice water, the product collected
  3. washwashed with water
  4. customdried

出典と根拠

ORDレコード
ord-ebb468054fb14b338818d917090eb205
出典データセット
uspto-grants-1977_05
特許番号
US04026936

反応ノート

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