2-(m-Nitrobenzamido)-1,5-naphthalenedisulfonic acid disodium salt → 2-(m-Aminobenzamido)-1,5-naphthalenedisulfonic acid disodium salt

HRID 2399133

反応式

[Na+:1].[Na+].[N+:3]([C:6]1[CH:7]=[C:8]([CH:30]=[CH:31][CH:32]=1)[C:9]([NH:11][C:12]1[CH:21]=[CH:20][C:19]2[C:18]([S:22]([O-:25])(=[O:24])=[O:23])=[CH:17][CH:16]=[CH:15][C:14]=2[C:13]=1[S:26]([O-:29])(=[O:28])=[O:27])=[O:10])([O-])=O.[H][H]>[Pd].O>[Na+:1].[Na+:1].[NH2:3][C:6]1[CH:7]=[C:8]([CH:30]=[CH:31][CH:32]=1)[C:9]([NH:11][C:12]1[CH:21]=[CH:20][C:19]2[C:18]([S:22]([O-:25])(=[O:24])=[O:23])=[CH:17][CH:16]=[CH:15][C:14]=2[C:13]=1[S:26]([O-:29])(=[O:28])=[O:27])=[O:10]

参加物

実験手順

A mixture of 25.0 g of 2-(m-(nitrobenzamido)-1,5-naphthalenedisulfonic acid disodium salt (prepared as in Example 1), 250 ml of water and 2.0 g of 10% palladium on charcoal is hydrogenated in a Parr shaker for 31/2 hours at room temperature with an initial pressure of 42 pounds of hydrogen. During this time a total of 11.5 pounds of hydrogen is absorbed.

後処理

custom2 hours
customat room temperature
customDuring this time a total of 11.5 pounds of hydrogen is absorbed

出典と根拠

ORDレコード: ord-bd5a3737ac4542e0ba13c41a9b8d6c1e
出典データセット: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04027038

反応式

参加物

反応物 2

生成物 1

試薬・触媒・溶媒 2

実験手順

後処理

出典と根拠

関連ノート