HCID 9250987、化合物 → HCID 16080835、化合物

HRID 2399278ノート

反応式

HRID 2399278 の反応式
[N+:1]([C:4]1[CH:20]=[CH:19][CH:18]=[CH:17][C:5]=1[O:6][C:7]1[CH:16]=[CH:15][CH:14]=[CH:13][C:8]=1[C:9]([O:11][CH3:12])=[O:10])([O-])=O>C(OCC)(=O)C.[Pd]>[NH2:1][C:4]1[CH:20]=[CH:19][CH:18]=[CH:17][C:5]=1[O:6][C:7]1[CH:16]=[CH:15][CH:14]=[CH:13][C:8]=1[C:9]([O:11][CH3:12])=[O:10]

参加物

4

反応物 1

HCID 9250987HCID 9250987、化合物

生成物 1

HCID 16080835HCID 16080835、化合物

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 8857Ethyl Acetate溶媒

実験手順

Methyl 2-(2-nitrophenoxy)benzoate (540 mg, 0.00198 mol) was dissolved in ethyl acetate (20 mL) and palladium on carbon catalyst (270 mg) was added. The mixture was hydrogenated at 57 psi for 2 h. The catalyst was filtered and the solvents were evaporated to yield the title compound. 1H NMR (250 MHz, CDCl3) δ7.83 (dd, 1H), 7.41 (m, 1H), 7.10 (m, 1H), 6.97 (m, 2H), 6.82 (m, 2H), 6.69 (m, 1H).

後処理

  1. filtrationThe catalyst was filtered
  2. customthe solvents were evaporated

出典と根拠

ORDレコード
ord-3aaeb6604fbb4331ac8a03762779fca0
出典データセット
uspto-grants-1995_09
特許番号
US05447957

反応ノート

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