Triethylamine → HCID 86676054、化合物

HRID 2405634

反応式

HRID 2405634 の反応式
C(N(CC)CC)C.[C:8](Cl)(=[O:12])[C:9]([CH3:11])=[CH2:10].[CH3:14][C:15]1([OH:24])[CH2:23][C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[CH2:16]1>C1(C)C=CC=CC=1>[C:8]([O:24][C:15]1([CH3:14])[CH2:23][C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[CH2:16]1)(=[O:12])[C:9]([CH3:11])=[CH2:10]

参加物

5

反応物 3

HCID 8471TriethylamineHCID 13528Methacryloyl chlorideHCID 5692202-Methyl-2-indanol

生成物 1

HCID 86676054HCID 86676054、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

With stirring and ice cooling, 111 g of triethylamine was added to a mixture of 120 g of methacrylic acid chloride, 200 g of 2-methyl-2-hydroxyindane, and 1500 g of toluene. The mixture was stirred at room temperature for 16 hours. By standard aqueous work-up and solvent distillation, a crude product was obtained. It was purified by column chromatography, yielding the target compound, 2-methylindan-2-yl methacrylate, designated Monomer 1.

後処理

  1. stirringThe mixture was stirred at room temperature for 16 hours
  2. distillationBy standard aqueous work-up and solvent distillation
  3. customa crude product was obtained
  4. customIt was purified by column chromatography

出典と根拠

ORDレコード
ord-fc74241a160b4f8fb760d6aa0848426a
出典データセット
uspto-grants-2014_08
特許番号
US08808966B2

関連ノート

読み込み中…