2-Fluorophenol → 2-Fluorophenyl sulfamate

反応式

C1([O:4][S:5](=[O:8])(=[O:7])[NH2:6])CC1.[F:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[OH:16]>>[F:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[NH:6][S:5](=[O:8])(=[O:7])[O-:4].[F:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[O:16][S:5](=[O:7])(=[O:4])[NH2:6]

参加物

反応物 2

HCID 97072-Fluorophenol

HCID 57785190Cyclopropyl sulfamate

生成物 2

HCID 539088522-Fluorophenyl sulfamate

HCID 866327902-Fluorophenylsulfamate

実験手順

2-Fluorophenylsulfamate was synthesized according to the method presented in the synthesis of Sulfamic acid cyclopropyl ester in Example 1 with the exception of utilizing 2-fluorophenol to obtain sulfamic acid 2-fluoro-phenyl ester.

出典と根拠

ORDレコード: ord-95faa3250a804849ace8520d82197ad7
出典データセット: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08809267B2

反応ノート

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