Sodium Iodide → Phosphinic acid, P-phenyl-P-(2,4,6-trimethylbenzoyl)-, sodium salt (1:1)

HRID 2413829ノート

反応式

HRID 2413829 の反応式
[CH3:1][C:2]1[CH:19]=[C:18]([CH3:20])[CH:17]=[C:16]([CH3:21])[C:3]=1[C:4]([P:6]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:9])[O:7]C)=[O:5].[I-].[Na+:23]>C(C(C)=O)C>[CH3:1][C:2]1[CH:19]=[C:18]([CH3:20])[CH:17]=[C:16]([CH3:21])[C:3]=1[C:4]([P:6]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:7])[O-:9])=[O:5].[Na+:23]

参加物

4

反応物 2

HCID 5238Sodium IodideHCID 20501383Methyl phenyl(2,4,6-trimethylbenzoyl)phosphinate

生成物 1

HCID 23690966Phosphinic acid, P-phenyl-P-(2,4,6-trimethylbenzoyl)-, sodium salt (1:1)

試薬・触媒・溶媒 1

HCID 6569Methyl Ethyl Ketone溶媒

反応条件

温度
55 °C

実験手順

60.5 parts by weight of methyl 2,4,6-trimethylbenzoylphenylphosphinate (as described in U.S. Pat. No. 4,265,723) and 33 parts by weight of sodium iodide were dissolved in 560 parts by volume of methyl ethyl ketone, and the solution was stirred for 2.5 hours at 55° C. The resulting precipitate was filtered off, washed with methyl ethyl ketone and dried, the desired product being obtained.

後処理

  1. filtrationThe resulting precipitate was filtered off
  2. washwashed with methyl ethyl ketone
  3. customdried

出典と根拠

ORDレコード
ord-a1a7ab26b1ce44cf9d62448b84b59e81
出典データセット
uspto-grants-1988_01
特許番号
US04719297

反応ノート

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