Sodium Iodide → HCID 13338394、化合物
反応式
[N:1]1([C:4]2[C:5]3[N:13]([CH2:14][CH3:15])[N:12]=[C:11]([CH3:16])[C:6]=3[N:7]=[C:8]([CH3:10])[N:9]=2)[CH2:3][CH2:2]1.[I-].[Na+]>CC(C)=O>[CH2:14]([N:13]1[C:5]2[C:4]3[N:9]([CH2:2][CH2:3][N:1]=3)[C:8]([CH3:10])=[N:7][C:6]=2[C:11]([CH3:16])=[N:12]1)[CH3:15]参加物
4
実験手順
The above aziridine (14 g, 0.065 mol) is dissolved in 150 ml acetone and 12 g (0.08 mol) of sodium iodide is added. The mixture is stirred overnight as a solid separates. The cooled mixture is filtered, the filter cake is washed with saturated NaHCO3 solution then water to yield 8 g (57%) of the title compound, mp 168°-170° C.
後処理
- filtrationThe cooled mixture is filtered
- washthe filter cake is washed with saturated NaHCO3 solution
出典と根拠
- ORDレコード
- ord-c358f2298b774c6ea15b5b92d7b141c3
- 出典データセット
- uspto-grants-1984_09
- 特許番号
- US04469868
反応ノート
読み込み中…