Ethanol → HCID 20311995、化合物

HRID 2420488ノート

反応式

HRID 2420488 の反応式
Cl[C:2]1[C:11](=[O:12])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4](=[O:13])[C:3]=1[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].[Na].[CH2:27]([OH:29])[CH3:28]>>[CH2:14]([C:3]1[C:4](=[O:13])[C:5]2[C:10]([C:11](=[O:12])[C:2]=1[O:29][CH2:27][CH3:28])=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

参加物

4

反応物 3

HCID 702EthanolHCID 1030502-Chloro-3-dodecyl-1,4-naphthoquinoneHCID 5360545Sodium

生成物 1

HCID 20311995HCID 20311995、化合物

実験手順

Eight parts of 3-chloro-2-n-dodecyl-1,4-naphthoquinone were added in one portion to a solution of 0.54 parts of sodium metal dissolved in 100 parts of ethyl alcohol at ambient temperature. The resulting dark suspension was heated at reflux for two hours. Excess ethyl alcohol was removed in vacuo and the dark residue was recrystallized from 2-propanol to yield 7.6 parts of 2-n-dodecyl-3-ethoxy-1,4-naphthoquinone, m.p. 36°-38° C.

後処理

  1. temperatureThe resulting dark suspension was heated
  2. temperatureat reflux for two hours
  3. customExcess ethyl alcohol was removed in vacuo
  4. customthe dark residue was recrystallized from 2-propanol

出典と根拠

ORDレコード
ord-d106ee23c6654a7ba1267b4973c63cca
出典データセット
uspto-grants-1978_08
特許番号
US04110473

反応ノート

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