(Phenylthio)acetic acid → (Phenylthio)acetyl chloride

HRID 246816

反応式

HRID 246816 の反応式
[C:1]1([S:7][CH2:8][C:9]([OH:11])=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(Cl)(=O)C([Cl:15])=O>C1(C)C=CC=CC=1>[C:1]1([S:7][CH2:8][C:9]([Cl:15])=[O:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

4

反応物 2

HCID 59541(Phenylthio)acetic acidHCID 65578Oxalyl chloride

生成物 1

HCID 4063350(Phenylthio)acetyl chloride

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

To a solution of 5.0 g of (phenylthio)acetic acid in 20 ml of toluene under nitrogen was added 5.2 ml of oxalyl chloride in four portions. The solution was stirred at room temperature for about twenty hours and then concentrated in vacuo to the oily title compound, which was used in subsequent reactions without further purificaton or characterization.

後処理

  1. concentrationconcentrated in vacuo to the oily title compound, which

出典と根拠

ORDレコード
ord-9ef97c2bf9824e38b8c136f32ff6aa57
出典データセット
uspto-grants-1987_11
特許番号
US04704386

関連ノート

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