HCID 54471129、化合物 → HCID 10856924、化合物

HRID 247688ノート

反応式

HRID 247688 の反応式
[CH2:1]1[CH2:16][O:15][CH:3]([CH2:4][CH:5]=[CH:6][C:7]2[CH:14]=[CH:13][C:10]([C:11]#[N:12])=[CH:9][CH:8]=2)[O:2]1>C1(C)C=CC=CC=1.[Pd]>[CH2:16]1[CH2:1][O:2][CH:3]([CH2:4][CH2:5][CH2:6][C:7]2[CH:14]=[CH:13][C:10]([C:11]#[N:12])=[CH:9][CH:8]=2)[O:15]1

参加物

4

反応物 1

HCID 54471129HCID 54471129、化合物

生成物 1

HCID 10856924HCID 10856924、化合物収率 82%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 1140Toluene溶媒

実験手順

A solution of 3.7 g of p-(4,4-ethylenedioxy-1-butenyl)benzonitrile in 50 ml of toluene was treated with 350 mg of palladium/carbon (5%) and the mixture was hydrogenated for 2.5 hours (hydrogen consumption 385 ml). The reaction mixture was then filtered (rinsing with diethyl ether) and the filtrate was evaporated. There were obtained 308 mg (82%) of p-(4,4-ethylenedioxybutyl)benzonitrile as a colourless, partially crystallizing oil.

後処理

  1. custom(hydrogen consumption 385 ml)
  2. filtrationThe reaction mixture was then filtered
  3. wash(rinsing with diethyl ether)
  4. customthe filtrate was evaporated

出典と根拠

ORDレコード
ord-fedc1941dc2744b9bc49bd9715bc2184
出典データセット
uspto-grants-1987_11
特許番号
US04709030

反応ノート

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