1-Decanol → 2-n-Decyloxycarbonylnaphthalene-6-carboxylic acid chloride

HRID 247796

反応式

HRID 247796 の反応式
[CH2:1]([OH:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH:12]1[C:21]2[C:16](=[CH:17][C:18]([C:22]([Cl:24])=[O:23])=[CH:19][CH:20]=2)[CH:15]=[CH:14][C:13]=1[C:25](Cl)=[O:26].C(N(CC)CC)C.CN(C1C=CC=CN=1)C>C(Cl)Cl>[CH2:1]([O:11][C:25]([C:13]1[CH:14]=[CH:15][C:16]2[C:21](=[CH:20][CH:19]=[C:18]([C:22]([Cl:24])=[O:23])[CH:17]=2)[CH:12]=1)=[O:26])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

参加物

6

反応物 4

HCID 81741-DecanolHCID 8471TriethylamineHCID 218852-DimethylaminopyridineHCID 34855962,6-Naphthalenedicarbonyl dichloride

生成物 1

HCID 543160202-n-Decyloxycarbonylnaphthalene-6-carboxylic acid chloride収率 56.3%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

After a solution of n-decyl alcohol (0.5 g), naphthalene-2,6-dicarboxylic acid dichloride (0.6 g), and triethylamine (0.27 g) and a very small amount of dimethylaminopyridine in methylene chloride (50 ml) was stirred at room temperature overnight, the solution was distilled to remove the solvent, until the titled compound (about 0.5 g) was obtained.

後処理

  1. distillationthe solution was distilled
  2. customto remove the solvent

出典と根拠

ORDレコード
ord-75e52ba2a4e54b1da4dfeb4197a82b67
出典データセット
uspto-grants-1993_05
特許番号
US05207947

関連ノート

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