Water → HCID 19764388、化合物

HRID 248146ノート

反応式

HRID 248146 の反応式
[H-].[Na+].[CH:3]([OH:21])=[CH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:22](Br)[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1.O.[CH3:31]N(C)C=O>>[C:23]1([CH2:22][O:21][CH2:3][C:4]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH2:31])[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1

参加物

6

反応物 5

HCID 962WaterHCID 6228Dimethylformamide2 回HCID 7498Benzyl BromideHCID 24758Sodium hydrideHCID 534378461-Octadecen-1-ol

生成物 1

HCID 19764388HCID 19764388、化合物

実験手順

To 1.4 g of washed sodium hydride in 100 ml of dry N,N-dimethylformamide is added a solution of 10 g of 1-octadecenol in 100 ml of dimethylformamide followed by 5.8 g of benzyl bromide. This mixture is stirred for 15 hours, then water added and the mixture extracted with ether. The ether extract is dried, evaporated and purified by chromatography, to give 9.0 g of the desired compound.

後処理

  1. extractionthe mixture extracted with ether
  2. extractionThe ether extract
  3. customis dried
  4. customevaporated
  5. custompurified by chromatography

出典と根拠

ORDレコード
ord-09f473ab93a349b9b56cb68124615b3c
出典データセット
uspto-grants-1993_05
特許番号
US05208223

反応ノート

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