Hydrochloric Acid → CFC-114a CFC-114

HRID 248230

反応式

HRID 248230 の反応式
[Cl:1][C:2]([Cl:8])([F:7])[C:3]([F:6])([F:5])[F:4].[Cl:9][C:10]([F:16])([F:15])[C:11]([Cl:14])([F:13])[F:12].[H][H].Cl.C(F)(F)C(F)F.C(F)(F)C(Cl)(F)F.C(F)C(F)(F)F.C(Cl)(F)C(F)(F)F>>[C:3]([F:6])([F:5])([F:4])[C:2]([Cl:8])([Cl:1])[F:7].[C:10]([Cl:9])([F:16])([F:15])[C:11]([Cl:14])([F:13])[F:12]

参加物

9

反応物 8

HCID 313Hydrochloric AcidHCID 6429Cfc 1143 回HCID 96321-Chloro-1,1,2,2-tetrafluoroethaneHCID 96671,1,2,2-TetrafluoroethaneHCID 97751,1-Dichloro-1,2,2,2-tetrafluoroethane2 回HCID 131291,1,1,2-TetrafluoroethaneHCID 17822Hcfc 124HCID 178418361HCID 178418361、化合物3 回

生成物 1

HCID 76970302CFC-114a CFC-114

実験手順

A mixture containing about 8% 2,2-dichloro-1,1,1,2-tetrafluoroethane (CFC-114a) and about 92% 1,2-dichloro-1,1,2,2-tetrafluoroethane (CFC-114) and hydrogen were fed to the reactor for a period of 477 hours. For an 3 hour period at 560° C., at an average time in synthesis of 275 hours, with a feed molar ratio of hydrogen to CFC-114/114a isomers of 2.2:1, and a liquid feed rate of 1.0 mL/hr of the combined 2,2-dichloro and the 1,2-dichloro isomers, the average conversion of the 2,2-dichloro isomer was 96% and the average conversion of the 1,2-dichloro isomer was 92%. The reactor effluent contained in addition to HCl and hydrogen, 17.4% HFC-134, 4.5% HCFC-124a and 2.0% CFC-114, as well as 2.0% HFC-134a, 0.5% HCFC-124 and 0.1% CFC-114a.

後処理

  1. waitFor an 3 hour period at 560° C.
  2. customat an average time in synthesis of 275 hours

出典と根拠

ORDレコード
ord-5b52ced4577442e7832a94956dbc2c9d
出典データセット
uspto-grants-1993_05
特許番号
US05208397

関連ノート

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