Dibutylamine → 1-Di-n-butylamino-5,5,7,7-tetramethyl-2-octene

HRID 249033

反応式

HRID 249033 の反応式
Cl[CH2:2][CH:3]=[CH:4][CH2:5][C:6]([CH3:13])([CH3:12])[CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9].[CH2:14]([NH:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:15][CH2:16][CH3:17].[O-2].[Mg+2]>C1COCC1.CCCCCC>[CH2:14]([N:18]([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:2][CH:3]=[CH:4][CH2:5][C:6]([CH3:13])([CH3:12])[CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9])[CH2:15][CH2:16][CH3:17]

参加物

6

反応物 3

HCID 8148DibutylamineHCID 1359701-Chloro-5,5,7,7-tetramethyl-2-octeneHCID 6850729Magnesium monoxide

生成物 1

HCID 538384691-Di-n-butylamino-5,5,7,7-tetramethyl-2-octene

試薬・触媒・溶媒 2

HCID 8028Tetrahydrofuran溶媒HCID 8058Hexane溶媒

実験手順

10 g (49.5 mmol) of 1-chloro-5,5,7,7-tetramethyl-2-octene, 64 g (495 mmol) of di-n-butylamine and 10 g (248 mmol) of magnesium oxide in 30 ml of THF are refluxed for 4.5 h. The mixture is taken up in 200 ml of hexane, extracted twice with 5% strength methanolic NaOH and once with water and dried at 30° C./1 mbar. Yield: quantitative.

後処理

  1. extractionextracted twice with 5% strength methanolic NaOH and once with water
  2. customdried at 30° C./1 mbar

出典と根拠

ORDレコード
ord-84a14235b1cd492588451c9f8e12a505
出典データセット
uspto-grants-1993_05
特許番号
US05212248

関連ノート

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