Azobisisobutyronitrile → 2-Phenylethenesulfonic acid

HRID 254137ノート

反応式

HRID 254137 の反応式
[CH:1]([S:9]([O-:12])(=[O:11])=[O:10])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[Na+].FC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.N(C(C)(C)C#N)=NC(C)(C)C#N>CS(C)=O>[CH:1]([S:9]([OH:12])(=[O:10])=[O:11])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

5

反応物 3

HCID 6547AzobisisobutyronitrileHCID 2782409Perfluorooct-1-ene2 回HCID 53627496Sodium styrenesulfonate

生成物 1

HCID 748642-Phenylethenesulfonic acid

試薬・触媒・溶媒 1

HCID 679Dimethyl Sulfoxide溶媒2 回

実験手順

19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of branched perfluorooctene (heptafluoro-3,3-bis(trifluoromethyl)-1-hexene) are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the branched perfluorooctene (5, 10, and 20 wt %).

後処理

  1. temperaturewith heating
  2. customThe monomers are polymerized for 24 hours or more

出典と根拠

ORDレコード
ord-edf865c9d65745a9ab3f6d0f1a499dd6
出典データセット
uspto-grants-2011_01
特許番号
US07875208B2

反応ノート

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