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Azobisisobutyronitrile → Styrenesulfonic Acid Allylhexafluoro-Isopropanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | 4-Penten-2-ol, 1,1,1-trifluoro-2-(trifluoromethyl)- | HCID 328870 | — |
| 反応物 | Sodium styrenesulfonate | HCID 53627496 | — |
| 溶媒 | Dimethyl Sulfoxide | HCID 679 | — |
| 生成物 | Styrenesulfonic Acid Allylhexafluoro-Isopropanol | HCID 131728620 | — |
反応手順
19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of 2-Allylhexafluoro-isopropanol are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the allylhexafluoro-isopropanol (2, 5, 10, and 20 wt %).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07875208B2 |
| 出典データセット | uspto-grants-2011_01 |
| ORD ID | ord-ed02a1056370470d86ee721b3d2d6bbb |
| 出典メモ | uspto-grants-2011_01 |