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HRID254138

反应详情

EQUATION

反应方程式

HRID 254138 的结构方程式

REACTANTS

反应物

3
结构：CC(C)(C#N)N=NC(C)(C)C#N
HCID6547

Azobisisobutyronitrile

C8H12N4

结构：C=CCC(O)(C(F)(F)F)C(F)(F)F
HCID328870

1,1,1-trifluoro-2-(trifluoromethyl)pent-4-en-2-ol

C6H6F6O

结构：O=S(=O)([O-])C=Cc1ccccc1.[Na+]
HCID53627496

Sodium 1-phenylethene-2-sulfonate

C8H7NaO3S

PRODUCTS

生成物

1
结构：C=CCC(O)(C(F)(F)F)C(F)(F)F.O=S(=O)(O)C=Cc1ccccc1
HCID131728620

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CS(C)=O
溶剂HCID679

Dimethyl sulfoxide

C2H6OS

2 次

PROCEDURE

实验过程

19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of 2-Allylhexafluoro-isopropanol are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the allylhexafluoro-isopropanol (2, 5, 10, and 20 wt %).

WORKUP

后处理

  1. temperaturewith heating
  2. customThe monomers are polymerized for 24 hours or more