Chloroform → N-ethoxymethyl-N-methylpyrrolidinium hexafluorophosphate

HRID 254902ノート

反応式

HRID 254902 の反応式
[Cl-].[CH2:2]([O:4][CH2:5][N+:6]1([CH3:11])[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH3:3].[F:12][P-:13]([F:18])([F:17])([F:16])([F:15])[F:14].[Na+].C(Cl)(Cl)Cl>O>[F:12][P-:13]([F:18])([F:17])([F:16])([F:15])[F:14].[CH2:2]([O:4][CH2:5][N+:6]1([CH3:11])[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH3:3]

参加物

5

反応物 3

HCID 6212ChloroformHCID 5147921Sodium hexafluorophosphateHCID 23116054N-ethoxymethyl-N-methylpyrrolidinium chloride

生成物 1

HCID 86618684N-ethoxymethyl-N-methylpyrrolidinium hexafluorophosphate収率 66.6%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

In 70.00 g of water was dissolved 35.00 g of N-ethoxymethyl-N-methylpyrrolidinium chloride and thereto was added 32.70 g of sodium hexafluorophosphate to obtain a white solid. The mixture was stirred for 30 minutes, and chloroform was added to the mixture for extraction. The extract was washed with 50 g of water 15 times, thereafter dried, giving 37.50 g of the desired product in the form of a white solid. The product was checked for 1H-NMR as in Example 1.

後処理

  1. customto obtain a white solid
  2. washThe extract was washed with 50 g of water 15 times
  3. customdried

出典と根拠

ORDレコード
ord-75f1e97b9fbd4866970b1db612a1b356
出典データセット
uspto-grants-2011_01
特許番号
US07875732B2

反応ノート

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