Naphthalene → Lithium Naphthalene

HRID 258220ノート

反応式

HRID 258220 の反応式
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.[Li:11]>>[Li:11].[CH:9]1[C:10]2[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=2)[CH:6]=[CH:7][CH:8]=1

参加物

3

反応物 2

HCID 931NaphthaleneHCID 3028194Lithium

生成物 1

HCID 57466756Lithium Naphthalene

実験手順

To a 1-liter, one-neck flask were added naphthalene (45 grams) and lithium shot (5.1 grams) in mineral oil. The flask was equipped with a magnetic stir bar, and was then capped with a rubber septum. After an argon purge, freshly distilled tetrahydrofuran (300 milliliters) was then added by cannula under argon and the mixture was stirred for 16 hours. The molarity of this initiator solution was 2.38 molar as determined by an average of the GPC molecular weight results from six polymerization reactions.

後処理

  1. customThe flask was equipped with a magnetic stir bar
  2. customwas then capped with a rubber septum
  3. customAfter an argon purge
  4. additionfreshly distilled tetrahydrofuran (300 milliliters) was then added by cannula under argon
  5. customresults from six polymerization reactions

出典と根拠

ORDレコード
ord-ae236520882a4396b981a026d5b28a16
出典データセット
uspto-grants-1993_11
特許番号
US05266438

反応ノート

読み込み中…