反応式
[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH2:3][CH:2]2[C:8]([OH:10])=[O:9]>C(O)C.[C].[Pd]>[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH2:3][CH:2]2[C:8]([OH:10])=[O:9]参加物
4
実験手順
15.7 g (110 mmol) of crude 5-norbornene-2-carboxylic acid was dissolved in 300 ml of ethanol, 1.55 g of 5% palladium-carbon powder was added, and the mixture was stirred under an atmosphere of hydrogen for 24 hours. After the catalyst was filtered off, the solvent was distilled off, and 14.5 g of crude 2-norbornanecarboxylic acid was obtained. Crude yield: 94%.
後処理
- filtrationAfter the catalyst was filtered off
- distillationthe solvent was distilled off
出典と根拠
- ORDレコード
- ord-450580ae0ff94758a4f9e307b836054b
- 出典データセット
- uspto-grants-1993_11
- 特許番号
- US05266728
関連ノート
読み込み中…