Hydrochloric Acid → Di-n-decyl-n-tetradecylmethylchloride

HRID 2589

反応式

HRID 2589 の反応式
[CH2:1]([C:11]([CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36])([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[Cl-:37].[Ca+2].[Cl-].Cl>C(Cl)Cl>[CH2:1]([C:11]([Cl:37])([CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 5284359Calcium ChlorideHCID 19690406Di-n-decyl-n-tetradecylcarbinol

生成物 1

HCID 19690403Di-n-decyl-n-tetradecylmethylchloride

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

One mole of di-n-decyl-n-tetradecylcarbinol is added to 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas is slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride is evaporated off to give di-n-decyl-n-tetradecyl-methylchloride.

後処理

  1. washThe product mixture is then washed with 1 liter of a 10% sodium carbonate solution
  2. dry with materialThe organic layer is dried with magnesium sulfate
  3. customthe methylene chloride is evaporated off

出典と根拠

ORDレコード
ord-3272ce8059be4591a93fe2fa3200dcab
出典データセット
uspto-grants-1998_03
特許番号
US05728907

関連ノート

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