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Isoquinoline → Desylisoquinolinium bromide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isoquinoline | HCID 8405 | — |
| 反応物 | 2-Bromo-1,2-diphenylethan-1-one | HCID 102630 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | Desylisoquinolinium bromide | HCID 21425396 | — |
反応手順
A solution of isoquinoline(10 g) and desylbromide (10 g) in dry benzene (50 ml) was stirred at 40° for seven hours. The suspension was allowed to stand overnight, and the benzene solution decanted off. The solid was ground to a powder, washed well with ether, and dried. Yield 12.3 g (85%), m.p. 239°-241° (Found C 68.3; H 4.6; N 3.4, Required C 68.3; H 4.5; N 3.5).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04035499 |
| 出典データセット | uspto-grants-1977_07 |
| ORD ID | ord-c0caa46ece104cd28f97510ceffa0466 |
| 出典メモ | uspto-grants-1977_07 |