Sodium Hydroxide → 4-Amino-5,6-dihydro-1-benzothiophen-7(4H)-one

HRID 259341ノート

反応式

HRID 259341 の反応式
Cl.[O:2]=[C:3]1[C:8]2[S:9][CH:10]=[CH:11][C:7]=2[CH:6]([NH2:12])[CH2:5][CH2:4]1.[OH-].[Na+]>O>[O:2]=[C:3]1[C:8]2[S:9][CH:10]=[CH:11][C:7]=2[CH:6]([NH2:12])[CH2:5][CH2:4]1

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 233477954,5,6,7-Tetrahydro-7-oxobenzo[b]thiophen-4-amine hydrochloride

生成物 1

HCID 233477964-Amino-5,6-dihydro-1-benzothiophen-7(4H)-one

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The free amine is obtained by neutralizing the amine hydrochloride in water with sodium hydroxide solution. It is separated by extraction with CHCl3 and removal of the CHCl3 in vacuo affords 4,5,6,7-tetrahydro-7-oxobenzo[b]thiophen-4-amine.

後処理

  1. customIt is separated by extraction with CHCl3 and removal of the CHCl3 in vacuo

出典と根拠

ORDレコード
ord-d354b11bc4894fd8a8ebc99a9b71a2f8
出典データセット
uspto-grants-1977_07
特許番号
US04036979

反応ノート

読み込み中…