Hydrochloric Acid → HCID 21422240、化合物

HRID 259531

反応式

HRID 259531 の反応式
[Cl:1][S:2]([OH:5])(=[O:4])=[O:3].[CH3:6][O:7][C:8]1[CH:9]=[C:10]([CH3:16])[CH:11]=[CH:12][C:13]=1[O:14][CH3:15].Cl>C1C=CC=CC=1>[S:2]([Cl:1])([OH:5])(=[O:4])=[O:3].[CH3:16][C:10]1[CH:9]=[C:8]([O:7][CH3:6])[C:13]([O:14][CH3:15])=[CH:12][CH:11]=1

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 24638Chlorosulfonic acidHCID 681263,4-Dimethoxytoluene

生成物 1

HCID 21422240HCID 21422240、化合物

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

23.2 gm (0.2 mol) of chlorosulfonic acid were slowly added dropwise to 15.2 gm (0.1 mol) of 3,4-dimethoxy-toluene at about - 10° C., while stirring and cooling. Afterwards, the mixture was allowed to warm to room temperature, and was then stirred until the evolution of hydrogen chloride ceased. The reaction mixture was poured over ice, and the precipitated sulfochloride was extracted with ether. The organic phase was successively washed with sodium bicarbonate solution and water, and then evaporated to dryness in vacuo. A turbid oil was obtained as a residue, which solidified after cooling. Rf -value (benzene): 0.5.

後処理

  1. temperaturecooling
  2. additionThe reaction mixture was poured over ice
  3. extractionthe precipitated sulfochloride was extracted with ether
  4. washThe organic phase was successively washed with sodium bicarbonate solution and water
  5. customevaporated to dryness in vacuo
  6. customA turbid oil was obtained as a residue
  7. temperatureafter cooling

出典と根拠

ORDレコード
ord-8da7098edd54451688031f7be482a051
出典データセット
uspto-grants-1977_07
特許番号
US04038407

関連ノート

読み込み中…