Allyltrimethylsilane → [{3-(Trimethylsilyl)propyl}dichlorosilyl]methane

HRID 260553

反応式

HRID 260553 の反応式
[Cl:1][SiH:2]([CH2:4][SiH](Cl)Cl)[Cl:3].[CH2:8]([Si:11]([CH3:14])([CH3:13])[CH3:12])[CH:9]=[CH2:10]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH3:12][Si:11]([CH3:14])([CH3:13])[CH2:8][CH2:9][CH2:10][Si:2]([CH3:4])([Cl:3])[Cl:1]

参加物

5

反応物 2

HCID 69808AllyltrimethylsilaneHCID 57370748Bisdichlorosilylmethane

生成物 1

HCID 13481742[{3-(Trimethylsilyl)propyl}dichlorosilyl]methane収率 145%

試薬・触媒・溶媒 2

HCID 61859Chloroplatinic acid触媒HCID 3776Isopropanol溶媒

実験手順

In the same apparatus and procedures as EXAMPLE 1, 9.3 g (0.04 mole) of bisdichlorosilylmethane, 13.7 g (0.12 mole) of allyltrimethylsilane, and 80 μl of 1% chloroplatinic acid solution in isopropanol were placed and reacted for 2 hours at reflux under the dry nitrogen atmosphere. Vacuum distillation gave 13.3 g (134°-136° C./0.05 mmHg) of [{3-(trimethylsilyl)propyl}dichlorosilyl]methane in 75.1% yield.

後処理

  1. customreacted for 2 hours
  2. temperatureat reflux under the dry nitrogen atmosphere
  3. distillationVacuum distillation

出典と根拠

ORDレコード
ord-ba7dde8b897a4feb8c7ca94e8a82e1f3
出典データセット
uspto-grants-1996_06
特許番号
US05527934

関連ノート

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