Water → 1-(1-Ethylpropylamino)-4-bromanthraquinone

HRID 260816

反応式

HRID 260816 の反応式
[CH2:1]([CH:3]([NH:6][C:7]1[C:20]2[C:19](=[O:21])[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:12](=[O:22])[C:11]=2[CH:10]=[CH:9][CH:8]=1)[CH2:4][CH3:5])[CH3:2].O.S([O-])([O-])=O.[Na+].[Na+].[Br:30]Br>C(O)(=O)C>[CH2:1]([CH:3]([NH:6][C:7]1[C:20]2[C:19](=[O:21])[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:12](=[O:22])[C:11]=2[C:10]([Br:30])=[CH:9][CH:8]=1)[CH2:4][CH3:5])[CH3:2]

参加物

6

反応物 4

HCID 962WaterHCID 24408Bromine3 回HCID 24437Sodium SulfiteHCID 229162751-(1-Ethylpropylamino)anthraquinone

生成物 1

HCID 229162741-(1-Ethylpropylamino)-4-bromanthraquinone

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒2 回

実験手順

EPAQ (20.02 g) was dissolved in hot acetic acid. In a separate flask, bromine (12.03 g) was dissolved in acetic acid (ca. 10 mL). The bromine solution was slowly added to the dye solution. The reaction was allowed to proceed for 1/2 hour, with occasional shaking. The reaction mixture was poured into water (600 mL), and aqueous sodium sulfite was added to discharge the bromine. The aqueous solution was decanted off. The solid was dissolved in methylene chloride and then concentrated and slowly added to cold methanol whereupon a solid precipitated.

後処理

  1. additionwas added
  2. customThe aqueous solution was decanted off
  3. dissolutionThe solid was dissolved in methylene chloride
  4. concentrationconcentrated
  5. additionslowly added to cold methanol whereupon a solid
  6. customprecipitated

出典と根拠

ORDレコード
ord-b5f6c7cee48b4300997d734cdd52d931
出典データセット
uspto-grants-1996_06
特許番号
US05530053

関連ノート

読み込み中…