Thionyl Chloride → alpha-(2-Acetoxy-5-chlorosulfonylphenylazo)acetoacetanilide

HRID 26122ノート

反応式

HRID 26122 の反応式
[C:1]([O:4][C:5]1[CH:10]=[CH:9][C:8]([S:11](O)(=[O:13])=[O:12])=[CH:7][C:6]=1[N:15]=[N:16][CH:17]([C:27]([CH3:29])=[O:28])[C:18]([NH:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)=[O:19])(=[O:3])[CH3:2].S(Cl)([Cl:32])=O>CN(C)C=O>[C:1]([O:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([Cl:32])(=[O:13])=[O:12])=[CH:7][C:6]=1[N:15]=[N:16][CH:17]([C:27]([CH3:29])=[O:28])[C:18]([NH:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)=[O:19])(=[O:3])[CH3:2]

参加物

4

反応物 2

HCID 24386Thionyl ChlorideHCID 23336111alpha-(2-Acetoxy-5-sulfophenylazo)acetoacetanilide

生成物 1

HCID 23336104alpha-(2-Acetoxy-5-chlorosulfonylphenylazo)acetoacetanilide

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

α-(2-Acetoxy-5-sulfophenylazo)acetoacetanilide (20 g) was added to thionyl chloride (100 ml). After the addition of dimethylformamide (4 ml), solution was complete, then followed by precipitation of the product. It was filtered off and dried in the vacuum oven at 40° C. Yield: 16.7 g, m.p. 225° to 226° C.

後処理

  1. customfollowed by precipitation of the product
  2. filtrationIt was filtered off
  3. customdried in the vacuum oven at 40° C

出典と根拠

ORDレコード
ord-cf01d4de27e3487eac128ffce1345f33
出典データセット
uspto-grants-1979_04
特許番号
US04148643

反応ノート

読み込み中…