Beta-Nitrostyrene → alpha-(Nitromethyl)benzyl diethyldithiocarbamate
反応式
[N+:1]([CH:4]=[CH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([O-:3])=[O:2].[CH2:12]([N:14]([CH2:18][CH3:19])[C:15](=[S:17])[S-:16])[CH3:13].C([NH2+]CC)C>C(=S)=S>[CH2:12]([N:14]([CH2:18][CH3:19])[C:15](=[S:16])[S:17][CH:5]([CH2:4][N+:1]([O-:3])=[O:2])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH3:13]参加物
4
実験手順
As in Example 17, reaction of β-nitrostyrene with diethylammonium diethyldithiocarbamate in the presence of carbon disulfide gave α-(nitromethyl)benzyl diethyldithiocarbamate melting at 81° C.-82.5° C. when recrystallized without heating from acetone-2-propanol solution.
出典と根拠
- ORDレコード
- ord-021db1f139f940299dd9a715ed39cc5e
- 出典データセット
- uspto-grants-1979_04
- 特許番号
- US04148795
反応ノート
読み込み中…