Allyl chloride → Ethyl vinylacetate

HRID 263308

反応式

HRID 263308 の反応式
[CH3:1][CH2:2][O-:3].[Na+].[OH-].[Na+].C(Cl)C=C.[CH2:11]([O:13][C:14](=[O:18])/[CH:15]=[CH:16]/[CH3:17])[CH3:12]>C(O)C.O>[CH2:11]([O:13][C:14](=[O:18])[CH2:15][CH:16]=[CH2:17])[CH3:12].[CH2:11]([O:13][C:14](=[O:18])[CH2:15][CH:16]([O:3][CH2:2][CH3:1])[CH3:17])[CH3:12]

参加物

8

反応物 4

HCID 7850Allyl chloride2 回HCID 14798Sodium HydroxideHCID 429065Ethyl trans-crotonateHCID 2723922Sodium ethoxide

生成物 2

HCID 74172Ethyl vinylacetate収率 89.5%HCID 14320732Ethyl 3-ethoxybutanoate収率 0.5%

試薬・触媒・溶媒 2

HCID 702Ethanol溶媒2 回HCID 962Water溶媒

実験手順

Same as Example 1, but with the use of 1.1 mole of sodium ethylate in the form of a solution of 14.5% by weight in ethanol with a content of 0.62 wt.-% of NaOH, and 200 ml of ethanol containing 0.28 wt.-% of H2O, one mole of allyl chloride is reacted at 1.5 at. and a pH of 10.0. The filtration and distillation yield 94.0 g of crotonic acid ethyl ester (yield 89.5%, 6.9 g of vinyl acetic acid ethyl ester (yield 6.6%) and 0.7 g of β-ethoxybutyric acid ethyl ester (yield 0.5%) for a transformation of 92.4% of the allyl chloride.

出典と根拠

ORDレコード
ord-70bcd220398e4b8a8bc60ad19ac96258
出典データセット
uspto-grants-1979_05
特許番号
US04156785

関連ノート

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