1,2-Dimethoxyethane → Anthracene

HRID 2637

反応式

HRID 2637 の反応式
C(COC)OC.[CH:7]1[C:20]2[C:11](=[CH:12][C:13]3[C:18]([CH:19]=2)=[CH:17][CH:16]=[CH:15][CH:14]=3)[CH:10]=[CH:9][CH:8]=1.[K]>CN1C(=O)CCC1>[CH:10]1[C:11]2[C:20](=[CH:19][C:18]3[C:13]([CH:12]=2)=[CH:14][CH:15]=[CH:16][CH:17]=3)[CH:7]=[CH:8][CH:9]=1

参加物

4

反応物 2

HCID 80711,2-DimethoxyethaneHCID 86741178Potassium Anthracene

生成物 1

HCID 8418Anthracene

試薬・触媒・溶媒 1

HCID 13387N-methyl-2-pyrrolidone溶媒

実験手順

A KAn solution is prepared as described in Example 20. The monoglyme is allowed to evaporate and the solid potassium anthracide complex collected. The melting point of the potassium anthracide crystals is >300° C. The dark-blue crystals turn white on exposure to air as a result of the radical-anion oxidation. Potassium anthracene salt is added to a solution of anhydrous NMP to give a 0.05M anthracene radical-anion solution resulting in the characteristic deep blue-black coloration of the solution. The KAn is stable in NMP. A sample of PTFE is treated in this bath and Pd seeded and electroless Cu subsequently plated as described in Example 17 with similar results.

後処理

  1. customA KAn solution is prepared
  2. customto evaporate
  3. customthe solid potassium anthracide complex collected
  4. customis >300° C
  5. customa result of the radical-anion oxidation

出典と根拠

ORDレコード
ord-cdd0d0c2b859493db6e0040c9ec93e28
出典データセット
uspto-grants-1998_03
特許番号
US05730890

関連ノート

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