m-Chloroperbenzoic acid → 8-methyl-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine

HRID 26513ノート

反応式

HRID 26513 の反応式
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[CH2:11][C:10]3=[N:12][N:13]=[C:14]([S:15][CH3:16])[N:9]3[CH:8]=[CH:7][C:6]=2[CH:17]=1.ClC1C=CC=C(C(OO)=[O:26])C=1>>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[CH2:11][C:10]3=[N:12][N:13]=[C:14]([S:15]([CH3:16])=[O:26])[N:9]3[CH:8]=[CH:7][C:6]=2[CH:17]=1

参加物

3

反応物 2

HCID 70297m-Chloroperbenzoic acidHCID 213233378-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine

生成物 1

HCID 213233748-methyl-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine

実験手順

By a procedure similar to that described in Example 17, 8-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine was reacted with m-chloroperbenzoic acid to obtain 8-methyl-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine. Colorless needles (as recrystallized from methanol), m.p. 158°-159° C.

出典と根拠

ORDレコード
ord-4a0886c085954195b57c67a493103931
出典データセット
uspto-grants-1979_04
特許番号
US04150139

反応ノート

読み込み中…