m-Chloroperbenzoic acid → 8-chloro-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine
反応式
[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[CH2:11][C:10]3=[N:12][N:13]=[C:14]([S:15][CH3:16])[N:9]3[CH:8]=[CH:7][C:6]=2[CH:17]=1.ClC1C=CC=C(C(OO)=[O:26])C=1>>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[CH2:11][C:10]3=[N:12][N:13]=[C:14]([S:15]([CH3:16])=[O:26])[N:9]3[CH:8]=[CH:7][C:6]=2[CH:17]=1参加物
3
実験手順
By a procedure similar to that described in Example 17, 8-chloro-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine was reacted with m-chloroperbenzoic acid to obtain 8-chloro-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine. Colorless needles (as recrystallized from methanol), m.p. 183°-185° C.
出典と根拠
- ORDレコード
- ord-05ba0d03e464488d9512763ed6ecce82
- 出典データセット
- uspto-grants-1979_04
- 特許番号
- US04150139
反応ノート
読み込み中…