Tributylamine → 4-(Chloromethyl)benzyltri-n-butylammonium chloride

HRID 266003

反応式

HRID 266003 の反応式
[CH2:1]([N:5]([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[Cl:14][CH2:15][C:16]1[CH:21]=[CH:20][C:19]([CH2:22][Cl:23])=[CH:18][CH:17]=1>CO>[Cl-:14].[Cl:23][CH2:22][C:19]1[CH:20]=[CH:21][C:16]([CH2:15][N+:5]([CH2:6][CH2:7][CH2:8][CH3:9])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:1][CH2:2][CH2:3][CH3:4])=[CH:17][CH:18]=1

参加物

4

反応物 2

HCID 7622TributylamineHCID 12171alpha,alpha'-Dichloro-p-xylene

生成物 1

HCID 867489774-(Chloromethyl)benzyltri-n-butylammonium chloride

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

A mixture of tri-n-butylamine (6 g, 32.2 mmol) and α,α'-dichloro-p-xylene (8 g, 46.0 mmol) in methanol (50 mL) was refluxed for 15 h after which time TLC examination showed completion of the reaction. Methanol was removed under reduced pressure to give an oily residue. The colorless oil was washed several times with toluene and hexane and then dried. The product obtained was used without further purification.

後処理

  1. temperaturewas refluxed for 15 h after which time TLC examination
  2. customcompletion of the reaction
  3. customMethanol was removed under reduced pressure
  4. customto give an oily residue
  5. washThe colorless oil was washed several times with toluene and hexane
  6. customdried
  7. customThe product obtained
  8. customwas used without further purification

出典と根拠

ORDレコード
ord-94af520978af41eebcbf90b1e0360f67
出典データセット
uspto-grants-1997_07
特許番号
US05650099

関連ノート

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