6H-Dibenzo(b,d)pyran-1-ol, 7,8,9,10-tetrahydro-3-(1,2-dimethylheptyl)-6,6,10-trimethyl- → 3-(3-methyl-2-octyl)-1-[4-(pyrrolidino)-butyryloxy]-7,8,9,10-tetrahydro-6,6,10-trimethyl-6H-dibenzo[b,d] pyran hydrochloride

HRID 267347

反応式

HRID 267347 の反応式
[OH:1][C:2]1[C:11]2[C:10]3[CH:12]([CH3:16])[CH2:13][CH2:14][CH2:15][C:9]=3[C:8]([CH3:18])([CH3:17])[O:7][C:6]=2[CH:5]=[C:4]([CH:19]([CH:21]([CH3:27])[CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH3:20])[CH:3]=1.[ClH:28].[N:29]1([CH2:34][CH2:35][CH2:36][C:37](O)=[O:38])[CH2:33][CH2:32][CH2:31][CH2:30]1>>[ClH:28].[CH3:27][CH:21]([CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH:19]([C:4]1[CH:3]=[C:2]([O:1][C:37](=[O:38])[CH2:36][CH2:35][CH2:34][N:29]2[CH2:33][CH2:32][CH2:31][CH2:30]2)[C:11]2[C:10]3[CH:12]([CH3:16])[CH2:13][CH2:14][CH2:15][C:9]=3[C:8]([CH3:17])([CH3:18])[O:7][C:6]=2[CH:5]=1)[CH3:20]

参加物

3

反応物 2

HCID 30450106H-Dibenzo(b,d)pyran-1-ol, 7,8,9,10-tetrahydro-3-(1,2-dimethylheptyl)-6,6,10-trimethyl-HCID 148556824-(Pyrrolidin-1-yl)butanoic acid hydrochloride

生成物 1

HCID 681356943-(3-methyl-2-octyl)-1-[4-(pyrrolidino)-butyryloxy]-7,8,9,10-tetrahydro-6,6,10-trimethyl-6H-dibenzo[b,d] pyran hydrochloride

実験手順

1-Hydroxy-3-(3-methyl-2-octyl)-7,8,9,10-tetrahydro-6,6,10-trimethyl-6H-dibenzo[ b,d] pyran from Example 32 is reacted with γ-pyrrolidinobutyric acid hydrochloride following the procedure of Example 9 to produce 3-(3-methyl-2-octyl)-1-[4-(pyrrolidino)-butyryloxy]-7,8,9,10-tetrahydro-6,6,10-trimethyl-6H-dibenzo[ b,d] pyran hydrochloride.

出典と根拠

ORDレコード
ord-9191a0948b794d8b99645a2735df241f
出典データセット
uspto-grants-1976_03
特許番号
US03941782

関連ノート

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