化工社化工社 化学情報印刷レポート · 研究参考用
Imidazole → [(6-Chlorohexyl)oxy](1,1-dimethylethyl)dimethylsilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Imidazole | HCID 795 | — |
| 反応物 | tert-Butyldimethylsilyl chloride | HCID 28928 | — |
| 反応物 | 6-Chloro-1-hexanol | HCID 74828 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | [(6-Chlorohexyl)oxy](1,1-dimethylethyl)dimethylsilane | HCID 10083489 | — |
反応手順
To 33 g. of dimethyl-tert-butylchlorosilane in 100 ml. of dimethylformamide is added 27 g. of 6-chlorohexan-1-ol and 340 g. of imidazole. The reaction mixture is allowed to stand at room temperature for 3 days to yield 6-chlorohexyloxy-dimethyl-tert-butylsilane, which is worked up by pouring into water, extracting with ether, washing with water, drying over calcium sulfate, removing the solvent by evaporation and purifying by distillation.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03943157 |
| 出典データセット | uspto-grants-1976_03 |
| ORD ID | ord-51e7c3f1df774dc0ae1737b6edcaaadb |
| 出典メモ | uspto-grants-1976_03 |