2-Ethylhexanol → Toluene 2,4-Diisocyanate

HRID 268149

反応式

HRID 268149 の反応式
[CH2:1]([CH:3]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4][OH:5])[CH3:2].[CH3:10][C:11]1[CH:16]=[CH:15][C:14]([N:17]=[C:18]=[O:19])=[CH:13][C:12]=1[N:20]=[C:21]=[O:22].C(C(C)=O)CCC>>[NH2:17][C:18]([O:5][CH2:4][CH3:3])=[O:19].[CH2:1]([CH:3]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4][OH:5])[CH3:2].[CH3:10][C:11]1[CH:16]=[CH:15][C:14]([N:17]=[C:18]=[O:19])=[CH:13][C:12]=1[N:20]=[C:21]=[O:22]

参加物

5

反応物 3

HCID 77202-EthylhexanolHCID 11443Toluene 2,4-DiisocyanateHCID 115832-Hexanone2 回

生成物 2

HCID 11443Toluene 2,4-DiisocyanateHCID 879616842-Ethylhexanol monourethane

実験手順

A 2-ethylhexanol monourethane of 2,4-toluene diisocyanate was prepared by adding 585.9 parts of 2-ethylhexanol to an agitated mixture of 783 parts of 2,4-toluene diisocyanate and 60 parts of methyl butyl ketone over approximately a 5-hour period with external cooling to maintain the reaction temperature below 30° C. After the addition was complete, an additional 30 parts of methylbutyl ketone was added; and the batch stored under dry nitrogen for subsequent use.

後処理

  1. temperaturewith external cooling
  2. temperatureto maintain the reaction temperature below 30° C
  3. additionAfter the addition

出典と根拠

ORDレコード
ord-faa885fa5f564f36a76f8977d6437fd5
出典データセット
uspto-grants-1976_03
特許番号
US03947338

関連ノート

読み込み中…