Chlorotriethylsilane → 3-Triethylsilyl-2-oxazolidinone

HRID 268304

反応式

HRID 268304 の反応式
[CH2:1]([Si:3]([CH2:7][CH3:8])([CH2:5][CH3:6])Cl)[CH3:2].[O:9]1[CH2:13][CH2:12][NH:11][C:10]1=[O:14]>>[CH2:1]([Si:3]([CH2:7][CH3:8])([CH2:5][CH3:6])[N:11]1[CH2:12][CH2:13][O:9][C:10]1=[O:14])[CH3:2]

参加物

3

反応物 2

HCID 13819ChlorotriethylsilaneHCID 739492-Oxazolidinone

生成物 1

HCID 214547763-Triethylsilyl-2-oxazolidinone

実験手順

Following the previous example, but replacing the trimethylchlorosilane with triethylchlorosilane (63.3 g; 0.42 mol) and operating under similar conditions, the result is the compound of the above heading; a colorless fluid liquid, obtained with a similar yield. 2-oxazolidinone, calculated: 42.82%; found; 42.70%. Distills at 100°C between 2 and 4 mm.

後処理

  1. customa colorless fluid liquid, obtained with a similar yield
  2. distillationDistills at 100°C between 2 and 4 mm

出典と根拠

ORDレコード
ord-158e83453e7449beb90a25edd87432d5
出典データセット
uspto-grants-1976_03
特許番号
US03947465

関連ノート

読み込み中…