1-Methylimidazole → Imidazolium cation
反応式
[Br:1][CH2:2][CH2:3][O:4][C:5]1[C:9]([CH3:10])=[CH:8][S:7][CH:6]=1.C[N:12]1[CH:16]=[CH:15][N:14]=[CH:13]1>>[Br:1][CH2:2][CH2:3][O:4][C:5]1[C:9]([CH3:10])=[CH:8][S:7][CH:6]=1.[NH+:12]1[CH:16]=[CH:15][NH:14][CH:13]=1参加物
4
実験手順
Similarly, monomer 2 is prepared from 3-(2-bromoethoxy)-4-methylthiophene (compound 4) and 1-methylimidazole (Aldrich Co.) (see Scheme 2). Compound 4 is prepared according to the procedure developed by Leclerc et al. (Faïd, K.; Leclerc, M. J. Chem. Soc., Chem. Commun., 2761, (1996)). The quaternization reaction between 1-methylimidazole and compound 4, provides the desired monomer imidazolium salt 2. (Lucas, P.; Mehdi, N. E.; Ho, H. A.; Belanger, D.; Breau, L. Synthesis, 9, 1253, (2000)).
出典と根拠
- ORDレコード
- ord-0f94149835124265b70e8f0810a9e23c
- 出典データセット
- uspto-grants-2008_11
- 特許番号
- US07446213B2
反応ノート
読み込み中…