Hydrochloric Acid → HCID 178503824、化合物

HRID 27095

反応式

HRID 27095 の反応式
Cl.NC1NC=C(CO)N=1.C1(C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C=1)[N+]([O-])=O.Cl.Cl.NCCS.[NH2:32][C:33]1[NH:34][CH:35]=[C:36]([CH2:38][S:39][CH2:40][CH2:41][NH2:42])[N:37]=1.[N+:43]([CH:46]=[C:47](SC)[S:48][CH3:49])([O-:45])=[O:44]>>[N+:43]([CH:46]=[C:47]([S:48][CH3:49])[NH:42][CH2:41][CH2:40][S:39][CH2:38][C:36]1[N:37]=[C:33]([NH2:32])[NH:34][CH:35]=1)([O-:45])=[O:44]

参加物

7

反応物 6

HCID 313Hydrochloric AcidHCID 9082Cysteamine HydrochlorideHCID 836231,1-Bis(methylthio)-2-nitroethyleneHCID 4432340PicrateHCID 178479151HCID 178479151、化合物HCID 178511470HCID 178511470、化合物

生成物 1

HCID 178503824HCID 178503824、化合物

実験手順

Reaction of 2-amino-4-hydroxymethylimidazole hydrochloride (which is obtained by treating the picrate salt with hydrochloric acid) with cysteamine hydrochloride and reaction of the resulting 2-amino-4-[(2-aminoethyl)thiomethyl]imidazole with 1-nitro-2,2-bis-methylthioethylene according to the procedure of Example 8(i) gives 1-nitro-2-methylthio-2-[2-((2-amino-4-imidazolyl)methylthio)ethylamino]ethylene. Finally, reaction with methylamine by the procedure of Example 8(ii) produces the title compound.

後処理

  1. customis obtained

出典と根拠

ORDレコード
ord-73e2bc23cb934fcd817da4efe00cec5c
出典データセット
uspto-grants-1980_09
特許番号
US04220652

関連ノート

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