2-Tert-Butylphenol → HCID 20094880、化合物

HRID 273939

反応式

HRID 273939 の反応式
[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].[C:12]1(C2NCCN=2)C=CC=C[CH:13]=1.C(=O)(OCC)OCC>CCCCCCCCCC>[CH2:12]([O:11][C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][C:5]=1[C:1]([CH3:4])([CH3:2])[CH3:3])[CH3:13]

参加物

5

反応物 3

HCID 69232-Tert-ButylphenolHCID 7766Diethyl CarbonateHCID 136392-Phenylimidazoline

生成物 1

HCID 20094880HCID 20094880、化合物

試薬・触媒・溶媒 1

HCID 15600Decane溶媒

反応条件

温度
140 °C

実験手順

5 mol of o-tert-butylphenol was charged into a reactor, along with 400 ml of decane and 5% of 4,5-dihydro-2-phenylimidazole, and the mixture was heated to 140° C. Then 5.5 mol of diethyl carbonate was added portionwise over a period of 4 hr. The resulting ethanol was continuously removed by distillation from the reaction mixture. After completion of the reaction, 4.6 mol of o-tert-butylphenyl ethyl ether was obtained from the mixture by distillation. The yield corresponded to 92% of theoretical, based on the starting amount of o-tert-butylphenol.

後処理

  1. customThe resulting ethanol was continuously removed by distillation from the reaction mixture
  2. customAfter completion of the reaction

出典と根拠

ORDレコード
ord-2d7976211b694e39b334e36fddd589f8
出典データセット
uspto-grants-1995_02
特許番号
US05387718

関連ノート

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