Triphenylphosphine → [(E)-cinnamyl]-triphenyl-phosphonium chloride

HRID 274192

反応式

HRID 274192 の反応式
[C:1]1([P:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:20]([Cl:29])[CH:21]=[CH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1>C1(C)C(C)=CC=CC=1>[Cl-:29].[CH2:20]([P+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)[CH:21]=[CH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1

参加物

4

反応物 2

HCID 11776TriphenylphosphineHCID 94242Benzene, (3-chloro-1-propenyl)-

生成物 1

HCID 73729[(E)-cinnamyl]-triphenyl-phosphonium chloride

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

反応条件

温度
130 °C

実験手順

88.2 parts of triphenylphosphine was dissolved in 240 parts of xylene and 51.3 parts of cinnamyl chloride was added thereto. The mixture was heated at 130° C. for 4 hr. After the mixture was cooled to 30° C., the resulting colorless crystals were collected by filtration and washed with toluene to obtain 117.4 parts of cinnamyltriphenylphosphonium chloride (compound No. 15).

後処理

  1. additionwas added
  2. temperatureAfter the mixture was cooled to 30° C.
  3. filtrationthe resulting colorless crystals were collected by filtration
  4. washwashed with toluene

出典と根拠

ORDレコード
ord-fa939c3d200942e0a4f0c4e26a59ee5a
出典データセット
uspto-grants-1995_02
特許番号
US05389486

関連ノート

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